Take the square to have side length $a$ (the ratio will not depend on $a$, so choosing $a=1$ earlier was only a simplification, not a restriction). Let $M$ be the midpoint of $AD$ and $N$ the midpoint of $BC$; the line $L = MN$ passes through the center of the square and is parallel to $AB$ and $CD$.
Because $P$ lies on line $L$, and $L$ is the perpendicular bisector of $AD$, triangle $APD$ is isosceles with $PA = PD$. Call this common length $r$. The apex angle at $P$ is given as $120^\circ$, so the two base angles at $A$ and $D$ are each $\frac{180^\circ - 120^\circ}{2} = 30^\circ$.
Drop a perpendicular from $P$ to $AD$; since the triangle is isosceles, this perpendicular bisects $AD$ and bisects the apex angle into two $60^\circ$ halves. In the resulting right triangle, the half-base is $\frac{a}{2}$ and the angle at $P$ is $60^\circ$, so:
\[\tan 60^\circ = \frac{a/2}{h} \quad\Rightarrow\quad h = \frac{a/2}{\sqrt3} = \frac{a}{2\sqrt3}\]where $h$ is the perpendicular distance from $P$ to side $AD$, which is exactly how deep triangle $APD$ cuts into the square. The area of triangle $APD$ is then:
\[[APD] = \frac12 \times a \times h = \frac12 \times a \times \frac{a}{2\sqrt3} = \frac{a^2}{4\sqrt3}\]By the mirror symmetry of the construction, triangle $BQC$ has exactly the same area $\frac{a^2}{4\sqrt3}$. The two removed triangles together have area $\frac{a^2}{2\sqrt3} = \frac{a^2\sqrt3}{6}$.
The whole square has area $a^2$, so the hexagon $ABCQPD$, being the square minus these two triangles, has area $a^2 - \frac{a^2\sqrt3}{6} = a^2\cdot\frac{6-\sqrt3}{6}$.
The required ratio of the hexagon's area to the remaining (removed) area is:
\[\frac{a^2(6-\sqrt3)/6}{a^2\sqrt3/6} = \frac{6-\sqrt3}{\sqrt3} = \frac{6}{\sqrt3} - \frac{\sqrt3}{\sqrt3} = 2\sqrt3 - 1\]The $a^2$ cancels out, confirming the ratio does not depend on the size of the square, exactly as it should not. This matches option (2), so the ratio is \(\boxed{2\sqrt3 - 1}\).