Step 1: Separate what the passage states as fact from what the statements claim.
The passage gives two pieces of information: combinatorics is "sometimes" used to model physical phenomena, and in such models probabilities are often assigned to combinatorial outcomes so that average values of physical quantities can be worked out.
Step 2: Test statement Q against the passage.
Q says modeling some physical phenomena uses probabilities on combinatorial possibilities to get average values. This is exactly what the passage describes in its last line. Nothing in Q goes beyond what the passage supports. So Q is TRUE.
Step 3: Test statement P against the passage.
P says combinatorics is always invoked in modeling physical phenomena. The word used in the passage is "sometimes", which is a weaker claim than "always". An "always" claim needs every case to hold, and the passage never says that. So P is FALSE.
Step 4: Match with the answer choices.
We need P false and Q true. Checking the four choices, only one option pairs a false P with a true Q, and the rest either make P true or make Q false, both of which go against what we found.
Step 5: State the result.
P is false because the passage only claims sometimes, not always. Q is true because it restates the passage directly.
\[ \boxed{\text{P is False and Q is True}} \]