Step 1: Idea behind the question:
The question asks which claim fails. Think about what photochemical smog needs: precursors and strong light.
Step 2: Look at the passage:
The passage names nitrogen oxides, volatile hydrocarbons and sunlight as the ingredients of Los Angeles smog. Light is the energy source.
Step 3: Test (1) and (2):
Statement (1) matches the passage, since smog sits near the ground. Statement (2) is also fine, because nitrogen oxides are brownish and colour the haze.
Step 4: Test (3):
At midday the sun is highest and the light is most intense. Reactions are quickest then, so the smog peak is at noon. This statement holds.
Step 5: Test (4):
Winter days have lower sun angle and less radiation. Less light means fewer photochemical reactions, so smog is worse in the warm season. This claim is the wrong one.
Step 6: Decide:
Only one statement is false, which is the winter claim.
Final Answer:
The incorrect statement is (4).
\[ \boxed{4} \]