Step 1: Use the molar volume
22.4 dm$^3$ of gas at STP holds $6.022\times10^{23}$ molecules, so the number of molecules is proportional to volume.
Step 2: Scale by the volume ratio
The given volume is $\dfrac{2.24}{22.4}=\dfrac{1}{10}$ of a molar volume.
\[ N = \frac{1}{10}\times 6.022\times10^{23} = 6.022\times10^{22} \]
So the number is one tenth of Avogadro's number, which is option (C).
Final Answer:
The sample is one tenth of a molar volume, so it has $6.022\times10^{22}$ molecules, option (C).
\[ \boxed{6.022\times10^{22}} \]