Step 1: Clock Hands Coincidence Principle.
The hour and minute hands of a clock align every \( 5 \frac{5}{11} \) minutes. Therefore, the duration between coincidences subsequent to 4 o'clock is computed as:
\[
T = \frac{60 \times 4}{11} = 218 \, \text{minutes} \, 49.1 \, \text{seconds}.
\]
Consequently, the approximate time of alignment after 4 o'clock is \( 04:21:49 \).
Final Answer: \[ \boxed{04:21:49 \, \text{o'clock}} \]