The potential energy of an electron in a hydrogen atom is negative, not positive. This negativity arises from the electrostatic attraction between the electron and the nucleus, as described by the formula: \[ U = -\frac{k e^2}{r} \] where \( U \) represents potential energy, \( k \) is Coulomb's constant, \( e \) is the elementary charge, and \( r \) is the electron-nucleus separation. Because the electron is bound, \( U \) must be negative.
The total energy of a bound charged particle, like an electron in a hydrogen atom, is the sum of its kinetic and potential energies. For this electron, the total energy is negative because the absolute value of the potential energy exceeds that of the kinetic energy.
Consequently, the assertion (that potential energy is negative) is true, while the reason (that total energy of a bound charged particle is negative) is also true, although the provided explanation incorrectly implies the opposite for the assertion.
Therefore, the correct answer is (D): Assertion is false but the reason is true.