Question:medium

Assertion (A) : Highest oxidation state of Mn is +7 in first series of transition elements.
Reason (R) : Transition metals exhibit variable oxidation states.

Show Hint

Scandium (+3) and Zinc (+2) are the only elements in the 3d series showing single oxidation states.
Mn shows the maximum number of oxidation states (+2 to +7) in the first series.
Variable oxidation state is a general property; specific values depend on the configuration.
Updated On: Jul 22, 2026
  • Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
  • Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
  • Assertion (A) is true, but Reason (R) is false.
  • Assertion (A) is false, but Reason (R) is true.
Show Solution

The Correct Option is B

Solution and Explanation

Step 1: Check the Assertion.
Manganese has the configuration $[\text{Ar}]3d^54s^2$, giving it 7 electrons available in the outer $3d$ and $4s$ levels. When all seven take part in bonding, manganese reaches $+7$, the highest oxidation state seen anywhere in the first transition series. So the Assertion is true.
Step 2: Check the Reason.
It is also a true general fact that transition metals show variable oxidation states, because both the $(n-1)d$ and $ns$ electrons lie close enough in energy to be used in bonding.
Step 3: Test whether the Reason explains the Assertion.
Saying transition metals show variable oxidation states is a broad statement that applies equally to iron, chromium or cobalt. It does not by itself explain why manganese in particular reaches all the way up to $+7$; that specific result comes from manganese having exactly five $3d$ and two $4s$ electrons all available for bonding.
Step 4: State the final match.
Both statements are true, but the Reason is too general to be the specific explanation for the Assertion.
\[ \boxed{\text{Both A and R true, R is not the correct explanation of A}} \]
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