Question

Assertion (A): [Cr(H_2O)_6]Cl_2 and [Fe(H_2O)_6]Cl_2 are examples of homoleptic complexes. 
Reason (R): All the ligands attached to the metal are the same.

• A. Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
• B. Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
• C. Assertion (A) is true, but Reason (R) is false.
• D. Assertion (A) is false, but Reason (R) is true.

Hint:

Homoleptic complexes contain only one type of ligand bound to the central metal atom.

Answer 1

The Correct Option is A

Homoleptic Complexes

Step 1: Understanding homoleptic complexes. Homoleptic complexes feature identical ligands coordinated to the central metal atom. For instance, both \([Cr(H_2O)_6]Cl_2\) and \([Fe(H_2O)_6]Cl_2\) are classified as homoleptic complexes because only water molecules serve as ligands in each.

Step 2: Conclusion. Assertion (A) is accurate, and Reason (R) provides a correct explanation for it. Therefore, option (A) is the correct choice.