Step 1: Use a divisor counting formula instead of listing multiples by hand.
For a fixed first roll \(a\), the values of \(b\) in \(\{1,\dots,6\}\) that are multiples of \(a\) are exactly \(a, 2a, 3a, \dots\) up to 6, so the count of favourable \(b\) values equals \(\left\lfloor \dfrac{6}{a} \right\rfloor\), the integer part of 6 divided by \(a\).
Step 2: Evaluate the floor function for each \(a\) from 1 to 6.
\(a=1: \lfloor 6/1 \rfloor = 6\)
\(a=2: \lfloor 6/2 \rfloor = 3\)
\(a=3: \lfloor 6/3 \rfloor = 2\)
\(a=4: \lfloor 6/4 \rfloor = \lfloor 1.5 \rfloor = 1\)
\(a=5: \lfloor 6/5 \rfloor = \lfloor 1.2 \rfloor = 1\)
\(a=6: \lfloor 6/6 \rfloor = 1\)
Step 3: Sum the floor values.
\[ \sum_{a=1}^{6} \left\lfloor \frac{6}{a} \right\rfloor = 6+3+2+1+1+1 = 14 \]
This sum is exactly the count of ordered pairs \((a,b)\) with \(a\) dividing \(b\), since each term counts the multiples of \(a\) available in the range.
Step 4: Since each value of \(a\) occurs with probability \(\frac{1}{6}\) and, given \(a\), the conditional probability that \(b\) is a multiple of \(a\) is \(\dfrac{\lfloor 6/a \rfloor}{6}\), the total probability is the average of these conditional probabilities:
\[ P = \frac{1}{6}\sum_{a=1}^{6} \frac{\lfloor 6/a \rfloor}{6} = \frac{14}{36} = \frac{7}{18} \]
Step 5: Conclude.
The floor sum method reproduces the same count of 14 favourable outcomes out of 36 obtained by direct listing, confirming the probability.
\[ \boxed{\dfrac{7}{18}} \]