Instead of listing all 36 outcomes, organize the count by fixing the first roll and asking "how many second-roll values make it a multiple?"
Since both rolls come from an unbiased die with faces $\{1,2,3,4,5,6\}$, the sample space has $6 \times 6 = 36$ equally likely ordered pairs $(a,b)$.
Go through each value of the first roll $a$ and count how many values of $b$ (from 1 to 6) are multiples of $a$:
- $a=1$: every face 1-6 is a multiple of 1, giving 6 matches.
- $a=2$: only 2, 4, 6 are multiples of 2 within the range, giving 3 matches.
- $a=3$: only 3 and 6 qualify, giving 2 matches.
- $a=4$: only 4 itself qualifies (8 is out of range), giving 1 match.
- $a=5$: only 5 itself qualifies, giving 1 match.
- $a=6$: only 6 itself qualifies, giving 1 match.
Adding these up: $6+3+2+1+1+1 = 14$ favorable ordered pairs out of 36 total.
Simplify: $\dfrac{14}{36} = \dfrac{7}{18}$.
$\text{Probability} = \dfrac{7}{18}$
Correct option: (C)