Step 1: Recall when quicksort performs worst.
In quicksort, the worst-case situation arises when the chosen pivot ends up at an extreme end of the array after partitioning.
This happens when the pivot is either the smallest or the largest element, producing one subarray of size $n-1$ and another of size zero.
Step 2: Identify the unfavorable pivot choices.
The array contains 25 distinct elements, and the pivot is selected uniformly at random.
Only two elements can lead to the worst-case split:
Thus, the number of unfavorable pivot choices is 2.
Step 3: Compute the probability.
Since each of the 25 elements is equally likely to be chosen as the pivot, the probability of selecting a worst-case pivot in the first partition is:
\[ \text{Probability} = \frac{2}{25} = 0.08 \]
Step 4: Final answer.
The computed probability is already expressed to two decimal places.
\[ \boxed{0.08} \]