Step 1: Analysis of (S1).
The condition for \( \frac{z - i}{z + i} \) to be purely real is that its imaginary part is zero. Given \( z = x + iy \), algebraic manipulation reveals that this condition, along with \( |z| = 1 \), yields exactly two solutions. Consequently, the set \( \{ z \in \mathbb{C} - \{-i\} : |z| = 1 \text{ and } \frac{z - i}{z + i} \text{ is purely real} \} \) contains two elements, confirming statement (S1).
Step 2: Analysis of (S2).
The condition for \( \frac{z - 1}{z + 1} \) to be purely imaginary is that its real part is zero. Algebraic analysis demonstrates that for \( |z| = 1 \), there are infinitely many solutions to this equation, as infinitely many points on the unit circle satisfy the zero real part condition for the quotient.
Therefore, statement (S2) is also correct.
Step 3: Conclusion.
The correct conclusion is: \[ \text{Only (S2) is correct}. \]