Option-elimination approach: the question wants the odd one out among emergency contraceptives.
Copper IUD (option 1) is in fact the gold standard for emergency contraception when placed within 5 days, with the lowest failure rate, so it stays. Mifepristone or RU 486 (option 2) is an antiprogestin proven as a postcoital agent, so it stays. High-dose estrogen (option 3), like the older Yuzpe regimen, is a valid if now less-used method, so it stays.
That leaves Danazol (option 4). Danazol is a weak androgen and gonadotropin suppressant used to treat endometriosis, menorrhagia, and fibrocystic breast disease. It has no role in preventing pregnancy after intercourse.
Hence the answer is Danazol. Ref: Dutta Gynaecology, 6th ed.