To determine the number of photons emitted per second, the formula for photon energy, \(E = h \cdot f\), is utilized. Here, \(h\) represents Planck's constant \((6.626 \times 10^{-34} \, \text{Js})\) and \(f\) denotes the frequency. The formula can be rearranged to calculate the photon count:
\(E = 6.626 \times 10^{-34} \, \text{Js} \times 5.0 \times 10^{14} \, \text{Hz} = 3.313 \times 10^{-19} \, \text{J}\)
\(n = \dfrac{\text{Power}}{\text{Energy per photon}} = \dfrac{3.31 \times 10^{-3} \, \text{W}}{3.313 \times 10^{-19} \, \text{J/photon}}\)
\(n = \dfrac{3.31 \times 10^{-3}}{3.313 \times 10^{-19}} \approx 1.0 \times 10^{16}\)
Consequently, the emission rate is approximately \(10^{16}\) photons per second. The corresponding option is: \(10^{16}\)