A shaft is subjected to pure torsion. The state of stress at any point on the surface of the shaft, relative to the axis of the shaft, consists of
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While the stress state relative to the shaft axis is pure shear, if you rotate the element by $45^\circ$, the stress state becomes pure normal stress (tensile and compressive stresses of magnitude equal to $\tau$).
This explains why brittle materials fail at $45^\circ$ under torsion.