Step 1: Take the ratio:
$\frac{P(X=4)}{P(X=2)} = \frac{\binom64p^4q^2}{\binom62p^2q^4} = \frac{p^2}{q^2}$, because the binomial coefficients are equal.
Step 2: Use the condition:
$9P(X=4) = P(X=2)$ means this ratio is $\frac19$, so $\frac pq = \frac13$.
Step 3: Solve:
$q = 3p$ and $p + q = 1$, so $4p = 1$, $p = 0.25$.
Final Answer:
p equals 0.25, option (C).
\[ \boxed{0.25} \]