To find the average velocity vector $ (\vec{v_{av}})$ for the particle moving from time $ t = 0 \, \text{s} $ to $ t = 5 \, \text{s} $, we will use the formula for average velocity:
$$ \vec{v_{av}} = \frac{\Delta \vec{r}}{\Delta t} $$
where $ \Delta \vec{r} $ is the change in position vector, and $ \Delta t $ is the change in time.
$$ \Delta \vec{r} = \vec{r_2} - \vec{r_1} = (13 \widehat{i} + 14 \widehat{j}) - (2 \widehat{i} + 3 \widehat{j}) $$
Simplifying, we get:
$$ \Delta \vec{r} = (13 - 2) \widehat{i} + (14 - 3) \widehat{j} = 11 \widehat{i} + 11 \widehat{j} $$
$$ \Delta t = 5 \, \text{s} - 0 \, \text{s} = 5 \, \text{s} $$
$$ \vec{v_{av}} = \frac{\Delta \vec{r}}{\Delta t} = \frac{11 \widehat{i} + 11 \widehat{j}}{5} = \frac{11}{5} \widehat{i} + \frac{11}{5} \widehat{j} $$
Thus, the average velocity vector from $ t = 0 \, \text{s} $ to $ t = 5 \, \text{s} $ is $ \frac{11}{5} ( \widehat{i} + \widehat{j}) $.
Hence, the correct answer is: $$ \frac{11}{5} ( \widehat{i} + \widehat{j}) $$.