Postmortem changes -- marbling:
Definition: Greenish-black/brownish network of discolouration along superficial veins, giving a marble-like appearance.
Mechanism:
- Putrefactive bacteria (gut flora) produce $\text{H}_2\text{S}$.
- $\text{H}_2\text{S}$ + haemoglobin (released by haemolysis) --> $\text{sulphaemoglobin}$ (greenish-black).
- This pigment diffuses into and stains the walls of superficial blood vessels.
Timeline:
- Onset: ~24 hours after death (internally).
- Naked-eye visibility: 36--48 hours after death.
Option analysis:
A -- Sulphaemoglobin pigment: CORRECT.
B -- Seen at 24 hours: Incorrect (visible at 36--48 h).
C -- Non-bacterial: Incorrect (bacterial H2S is the cause).
D -- Lightning: Incorrect (lightning causes Lichtenberg figures).
\[\boxed{\text{It is due to sulphaemoglobin pigment}}\]