Step 1: List out all 27 small cubes by type.
In a cube cut into 3 equal parts on every edge, the 27 pieces split as 8 corner cubes (3 faces painted each), 12 edge cubes (2 faces painted each), 6 face-centre cubes (1 face painted each) and 1 centre cube (0 faces painted). Check the total: $8+12+6+1=27$, which matches the cube we have.
Step 2: Focus only on the group with a single painted face.
The question asks about cubes with just one painted face, so only the 6 face-centre cubes are relevant here, one sitting at the middle of each of the 6 outer faces of the big cube.
Step 3: Filter by colour.
Of these 6 outer faces, 2 are Black (top and bottom) and 4 are Green (the four side faces). So among the 6 face-centre cubes, 2 of them show a Black face and the other 4 show a Green face.
Step 4: Pick out the ones the question wants.
Since the question asks specifically for one face painted and that face is Black, we keep only the 2 face-centre cubes belonging to the top and bottom faces.
Final Answer:
There are 2 such smaller cubes.
\[ \boxed{2} \]