Question:medium

‘A’ and ‘B’ respectively are: \(A\xrightarrow[(2)Zn-H_2O]{(1)O_3}\)
\(Ethane-1, 2-dicarbaldehyde + Glyoxal/Oxaldehyde\)
\(B \xrightarrow[(2)Zn-H_2O]{(1)O_3}   5 - oxohexanal\)

Updated On: Mar 20, 2026
  • \(1-methylcyclohex-1, 3-diene \;\& \;cyclopentene\)
  • \(Cyclohex-1, 3-diene \;\& \;cyclopentene\)
  • \(1-methylcyclohex-1, 4-diene \;\& \;1-methylcyclo-pent-ene\)
  • \(Cyclohex-1, 3-diene \;\&\; 1-methylcyclopent-1-ene\)
Show Solution

The Correct Option is D

Solution and Explanation

To solve this problem, we need to understand the ozonolysis reaction applied to the given compounds and how it leads to the formation of the specified products.

  1. A \xrightarrow[(2)Zn-H_2O]{(1)O_3} Ethane-1, 2-dicarbaldehyde + Glyoxal
    • Ozonolysis of A leading to the formation of ethane-1, 2-dicarbaldehyde (glyoxal or oxaldehyde) indicates that A must have a structure that breaks into two aldehyde groups.
    • The only diene option in the list that would break into simple aldehydes upon ozonolysis is Cyclohex-1, 3-diene. Ozonolysis of this compound results in two smaller aldehyde molecules: ethane-1, 2-dicarbaldehyde and another aldehyde or ketone depending on the substituents.
  2. B \xrightarrow[(2)Zn-H_2O]{(1)O_3} 5 - oxohexanal
    • Ozonolysis of B yielding 5-oxohexanal suggests that the compound has a structure that can be cleaved to form a six-carbon chain with a ketone and an aldehyde group.
    • For 1-methylcyclopent-1-ene, ozonolysis can lead to a linear compound containing an aldehyde and ketone, matching the product 5-oxohexanal. The presence of the methyl group shifts such a cleavage.

After analyzing both reactions, we can conclude:

  • A = Cyclohex-1, 3-diene
  • B = 1-methylcyclopent-1-ene

Therefore, the correct answer is Cyclohex-1, 3-diene \;&\; 1-methylcyclopent-1-ene.

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