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List of top Chemistry Questions on Electrochemical Cells asked in CBSE CLASS XII

The following reactions occur at the anode during the electrolysis of aqueous sodium chloride solution: \[ Cl^-_{(aq)} \rightarrow \frac{1}{2}Cl_2(g)+e^- \qquad E^\circ_{\text{cell}}=1.36\,V \] \[ 2H_2O(l) \rightarrow O_2(g)+4H^+(aq)+4e^- \qquad E^\circ_{\text{cell}}=1.23\,V \] Which reaction is feasible at the anode and why?
  • CBSE Class XII - 2026
  • CBSE Class XII
  • Chemistry
  • Electrochemical Cells
Write anode, cathode and overall reaction involved in dry cell.
  • CBSE Class XII - 2026
  • CBSE Class XII
  • Chemistry
  • Electrochemical Cells

The elements of the 3d transition series are given as: Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn. Answer the following:

Copper has an exceptionally positive \( E^\circ_{\text{M}^{2+}/\text{M}} \) value, why?

  • CBSE Class XII - 2025
  • CBSE Class XII
  • Chemistry
  • Electrochemical Cells

Assertion (A): Cu cannot liberate \( H_2 \) on reaction with dilute mineral acids. 
Reason (R): Cu has positive electrode potential.

  • CBSE Class XII - 2025
  • CBSE Class XII
  • Chemistry
  • Electrochemical Cells
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